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- Title
Crystal Structure of the Cyano-Bridged Coordination Copper(I) Complex [Cu<sub>8</sub>(dpe)<sub>4</sub>(CN)<sub>8</sub>]·2dpe·H<sub>2</sub>O.
- Authors
Ermolaev, A. V.; Sukhikh, T. S.; Mironov, Y. V.
- Abstract
Cyano-bridged layered coordination polymer [Cu8(dpe)4(CN)8]·2dpe·H2O (1) is prepared by the hydrothermal reaction of CuCN and dpe (dpe = 1,2-di-4-pyridylethylene) in the presence of Cs3K[Re6S8(CN)6]·2H2O. The [Cu8(dpe)4(CN)8] complex is an isomer of the earlier described [Cu2(CN)2(dpe)] with a 3D framework structure. The structure of 1 is triclinic, space group, a = 11.9229(8) Å, b = 11.9549(8) Å, c = 14.1984(10) Å, α = 102.019(2)°, β = 102.370(2)°, γ = 104.151(2)°, V = 1842.8(2) Å3, Z = 1, dcalc = 1.647 g/cm3. The Cu atoms in 1 have a triangular coordination environment formed by N atoms of the bridging dpe molecule and N and C atoms of the ambidentate bridging CN ligands.
- Subjects
COPPER; CRYSTAL structure; COORDINATION polymers; SPACE groups; STRUCTURAL frames; ISOMERS; ATOMS
- Publication
Journal of Structural Chemistry, 2024, Vol 65, Issue 4, p771
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S0022476624040127