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- Title
Bromidovanadium(II, III, and IV) Complexes.
- Authors
Rehder, Dieter; Nekola, Henning; Behrens, Axel; Cramer, Stephen P.; Funk, Tobias
- Abstract
The bromidovanadium complexes cis-[VIIBr2(bith)] ( 1) [bith = 1,6-bis(2-benzimidazolyl)-2,5-dithiahexane], cis-[VIIBr2(pth)] ( 2a) [pth = 1,6-bis(2-pyridyl)-2,5-dithiahexane], cis-[VIIIBr2(pth)]Br ( 2b), trans-[VIIBr2(tmeda)2] ( 3) (tmeda = tetramethylethylenediamine), fac-[VIIIBr3(9S3)] ( 4) (9S3 = 1, 4, 7-trithiacyclononane), mer-[VIIIBr3(thf)3] ( 5) (thf = tetrahydrofurane), and trans-[VIVOBr2(thf)2H2O] ( 6) were prepared and characterized by, inter alia, XRD ( 5, 6), K-edge XAS ( 3, 4) or L-edge XAS ( 2a, 2b). The complexes are also addressed in the context of the potential of halogenidovanadium compounds in catalytically conducted reactions, including biogenic processes.
- Subjects
METAL complexes; CHEMICAL reactions; BIOGENIC amines; VANADIUM; HYDROGENATION
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2013, Vol 639, Issue 8/9, p1401
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201300049