We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Photocycloaddition of Cyclohex-2-enones to 2-Alkylprop-2-enenitriles.
- Authors
Meyer, Lars; Elsholz, Bruno; Reulecke, Ingo; Schmidt, Kerstin; Margaretha, Paul; Wessig, Pablo
- Abstract
The outcome of the photocycloaddition of cyclohex-2-enones to 2-alkylprop-2-enenitriles differs basically from that of the corresponding 2-alkylbut-1-en-3-ynes. While the latter afford mainly products resulting from 1,6-cyclization of the intermediate triplet alkyl-(prop-2-ynyl) 1,4-biradical, the former give only cyclobutanecarbonitriles resulting from 1,4-cyclization of the singlet alkyl-cyanoalkyl 1,4-biradical.
- Publication
Helvetica Chimica Acta, 2002, Vol 85, Issue 7, p2065
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/1522-2675(200207)85:7<2065::AID-HLCA2065>3.0.CO;2-S