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- Title
Microporous Polymers from a Carbazole-Based Triptycene Monomer: Synthesis and Their Applications for Gas Uptake.
- Authors
Zhai, Tian ‐ Long; Tan, Liangxiao; Luo, Yi; Liu, Jun ‐ Min; Tan, Bien; Yang, Xiang ‐ Liang; Xu, Hui ‐ Bi; Zhang, Chun
- Abstract
Two kinds of novel organic microporous polymers TCPs ( TCP-A and TCP-B) were prepared by two cost-effective synthetic strategies from the monomer of tricarbazolyltriptycene ( TCT). Their structure and properties were characterized by FT-IR, solid 13C NMR, powder XRD, SEM, TEM, and gas absorption measurements. TCP-B displayed a high surface area (1469 m2 g−1) and excellent H2 storage (1.70 wt % at 1 bar/77 K) and CO2 uptake abilities (16.1 wt % at 1 bar/273 K), which makes it a promising material for potential application in gas storage.
- Subjects
POLYMER research; MONOMERS; CARBAZOLE; CHEMICAL synthesis; CARBON dioxide; GAS storage
- Publication
Chemistry - An Asian Journal, 2016, Vol 11, Issue 2, p294
- ISSN
1861-4728
- Publication type
Article
- DOI
10.1002/asia.201501105