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- Title
Application of singular value decomposition analysis to time-dependent powder diffraction data of an in-situ photodimerization reaction.
- Authors
Mabied, Ahmed F.; Shunsuke Nozawa; Manabu Hoshino; Ayana Tomita; Tokushi Sato; Shin-ichi Adachi
- Abstract
Singular value decomposition (SVD) analysis has important applications for time-dependent crystallographic data, extracting significant information. Herein, a successful application of SVD analysis of time-resolved powder diffraction data over the course of an in-situ photodimerization reaction of anthracene derivatives is introduced. SVD revealed significant results in the case of 9-methylanthracene and 1-chloroanthracene. The results support the formation of the 9-methylanthracene stable dimer phase and suggest the existence of an excimer state.
- Subjects
PHOTODIMERIZATION; DATA analysis; PHOTOCHEMISTRY; POWDERS; QUANTUM counters
- Publication
Journal of Synchrotron Radiation, 2014, Vol 21, Issue 3, p554
- ISSN
0909-0495
- Publication type
Article
- DOI
10.1107/S1600577514004366