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- Title
SYNTHESIS AND STRUCTURE OF SILICON-CONTAINING CAGES.
- Authors
Hankin, Joseph A.; Howe, Ray W.; Damrauer, Niels H.; Peterson, Kelly A.; Bruner, Stephen J.; Damrauer, Robert
- Abstract
The synthesis and properties of two new silicon-containing cage systems are reported. These are prepared by transition metal-catalyzed cyclotrimerizations of siliconcontaining tripod triynes. Trimerizations of this type give both 1,2,4 and 1,3,5 benzene ring isomers. These isomers have been separated and characterized by a variety of means including multi-nuclear NMR and X-ray analysis. Collaborative ab initio computations have been carried out to examine the stability of in versus out isomers in related cage systems.
- Publication
Main Group Metal Chemistry, 1994, Vol 17, Issue 6, p391
- ISSN
0792-1241
- Publication type
Article