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- Title
Acidic-basic interactions in tungstate melts based on tungsten electroplating out of them.
- Authors
OnischENko, V. A.; Soloviev, V. V.; ChernENko, L. A.; Malyshev, V. V.; Bondus, S. N.
- Abstract
Based on thermodynamic calculations of possible reactions of interaction between sodium tungstate and oxygen-containing compounds of boron, carbon, phosphor, sulphur, metals of VI-B group the probability of possible reactions was evaluated. The experimental verification of the assumptions was accomplished by the methods of potentiometry and IR-spectroscopy. The possibility of existence of equilibrium (reversible) melted systems with the electrodes from metals of VI-B group and their carbides was proved by the electrochemical measurements and thermodynamic calculations.
- Subjects
TUNGSTATES; TUNGSTEN compounds; POLYOXOTUNGSTATES; TUNGSTEN; CHROMIUM group
- Publication
Materialwissenschaft und Werkstoffechnik, 2014, Vol 45, Issue 11, p1030
- ISSN
0933-5137
- Publication type
Article
- DOI
10.1002/mawe.201400222