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- Title
Photoelectrochemical C−H Alkylation of Heteroarenes with Organotrifluoroborates.
- Authors
Yan, Hong; Hou, Zhong‐Wei; Xu, Hai‐Chao
- Abstract
A photoelectrochemical method for the C−H alkylation of heteroarenes with organotrifluoroborates has been developed. The merger of electrocatalysis and photoredox catalysis provides a chemical oxidant‐free approach for the generation and functionalization of alkyl radicals from organotrifluoroborates. A variety of heteroarenes were functionalized using primary, secondary, and tertiary alkyltrifluoroborates with excellent regio‐ and chemoselectivity.
- Subjects
PHOTOELECTROCHEMISTRY; CARBON-hydrogen bonds; ALKYLATION; HETEROARENES; OXIDATION-reduction reaction
- Publication
Angewandte Chemie, 2019, Vol 131, Issue 14, p4640
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201814488