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- Title
The EPR Spectrum of Triplet Mesitylphosphinidene: Reassignment and New Assignment.
- Authors
Akimov, Alexander V.; Ganushevich, Yulia S.; Korchagin, Denis V.; Miluykov, Vasili A.; Misochko, Eugenii Y.
- Abstract
Low-temperature UV-photolysis of mesitylphosphiranes under highly anaerobic conditions leads to the formation of the triplet mesitylphosphinidene (MesP). The recorded X-band EPR spectrum of triplet MesP and the derived zero-field splitting parameter D=4.116 cm−1 differ significantly from those reported previously for this intermediate. New magnetic parameters of mesitylphosphinidene are discussed along with the results of DFT calculations.
- Subjects
ELECTRON paramagnetic resonance spectroscopy; PHOSPHINIDENES; ULTRAVIOLET photolysis; HYPERFINE structure; DENSITY functional theory
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 27, p8052
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201703629