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- Title
Asymmetric Copper-Catalyzed Carbomagnesiation of Cyclopropenes.
- Authors
Dian, Longyang; Müller, Daniel S.; Marek, Ilan
- Abstract
The highly diastereo- and enantioselective formation of polysubstituted cyclopropanes was easily achieved through the asymmetric copper-catalyzed carbomagnesiation reaction of nonfunctionalized cyclopropene derivatives. The carbometalated species generated in situ readily undergo C−C and C−X bond-forming reactions with various electrophiles with complete retention of configuration.
- Subjects
COPPER catalysts; ASYMMETRY (Chemistry); CYCLOPROPENE; CHEMICAL derivatives; SUBSTITUENTS (Chemistry)
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 24, p6887
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201701094