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- Title
Hydrodehalogenation of Haloarenes by a Sodium Hydride-Iodide Composite.
- Authors
Ong, Derek Yiren; Tejo, Ciputra; Xu, Kai; Hirao, Hajime; Chiba, Shunsuke
- Abstract
A simple protocol for hydrodebromination and -deiodination of halo(hetero)arenes was enabled by sodium hydride (NaH) in the presence of lithium iodide (LiI). Mechanistic studies showed that an unusual concerted nucleophilic aromatic substitution operates in the present process.
- Subjects
ARYL halides; SODIUM hydride; AROMATIC compounds; LITHIUM; ALKALI metals
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 7, p1866
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201611495