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- Title
Palladium-Catalyzed Direct CH Functionalization of Benzoquinone.
- Authors
Walker, Sarah E.; Jordan-Hore, James A.; Johnson, David G.; Macgregor, Stuart A.; Lee, Ai-Lan
- Abstract
A direct Pd-catalyzed CH functionalization of benzoquinone (BQ) can be controlled to give either mono- or disubstituted BQ, including the installation of two different groups in a one-pot procedure. BQ can now be directly functionalized with aryl, heteroaryl, cycloalkyl, and cycloalkene groups and, moreover, the reaction is conducted in environmentally benign water or acetone as solvents.
- Subjects
CHEMICAL synthesis; PALLADIUM catalysts; BENZOQUINONES; CARBON-hydrogen bonds; MOLECULAR electronics; REGIOSELECTIVITY (Chemistry); HALOGENATION
- Publication
Angewandte Chemie, 2014, Vol 126, Issue 50, p14096
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201408054