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- Title
Zinc(II) Complexes with Tetrafluoroterephthalic and Octafluorobiphenyl-4,4′-dicarboxylic Acid Anions and 1,10-Phenanthroline.
- Authors
Rakhmanova, M. I.; Glinskaya, L. A.; Larionov, S. V.; Naumov, D. Yu.; Fadeeva, V. P.; Vinogradov, A. S.; Karpov, V. M.; Platonov, V. E.
- Abstract
Zinc(II) complexes with 1,10-phenanthroline and tetrafluoroterephthalate and octafluorobiphenyl 4,4′-dicarboxylate anions have been synthesized. According to the IR spectral data, the complexation involves coordination of the metal ion to the nitrogen atoms of phenanthroline and carboxylate oxygen atom of the acid anion. The complexes show photoluminescence in the visible region of the spectrum. The structure of the complex salt [Zn(H2O)6][Zn(H2O)4(L2)2] · H2O, where L2 is octafluorobiphenyl-4,4′-dicarboxylate anion (monodentate ligand), has been determined by X-ray analysis.
- Subjects
ZINC compounds; PHOTOLUMINESCENCE; PHENANTHROLINE; COORDINATION polymers; CARBOXYLATES
- Publication
Russian Journal of General Chemistry, 2019, Vol 89, Issue 2, p261
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363219020154