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- Title
Switchable 2,2,2-Trifluoroethylation and gem-Difluorovinylation of Organoboronic Acids with 2,2,2-Trifluorodiazoethane.
- Authors
Wu, Guojiao; Deng, Yifan; Wu, Chaoqiang; Wang, Xi; Zhang, Yan; Wang, Jianbo
- Abstract
The transition-metal-free 2,2,2-trifluoroethylation and gem-difluorovinylation of arylboronic acids were developed. By employing different reaction conditions, these transformations provide both (2,2,2-trifluoroethyl)arenes and gem-difluorovinylarenes from arylboronic acids and 2,2,2-trifluorodiazoethane. The operation is simple and scalable with good functional group tolerance.
- Subjects
FLUORINE; BORON; DIAZO compounds; AROMATIC compounds; ORGANIC chemistry research
- Publication
European Journal of Organic Chemistry, 2014, Vol 2014, Issue 21, p4477
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201402597