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- Title
Hidden Flexibility of Strychnine.
- Authors
Schmidt, Manuel; Reinscheid, Frauke; Sun, Han; Abromeit, Hans; Scriba, Gerhard K. E.; Sönnichsen, Frank D.; John, Michael; Reinscheid, Uwe M.
- Abstract
The prototypic molecule for conformational rigidity, that is, strychnine, exhibits fast conformational exchange on the NMR timescale at room temperature. A comprehensive description of this up-to-now-hidden stereodynamic behavior is presented, which combines experimental and computational data.
- Subjects
STRYCHNINE; CONFORMATIONAL analysis; ORGANIC chemistry research; ORGANIC synthesis; NUCLEAR magnetic resonance
- Publication
European Journal of Organic Chemistry, 2014, Vol 2014, Issue 6, p1147
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201301760