We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Synthesis of C-Disaccharides through a One-Pot Alkynol Cycloisomerization-Reductive Deoxygenation.
- Authors
Narute, Sachin B.; Rout, Jeetendra Kumar; Ramana, Chepuri V.
- Abstract
A sweet disposition: Simple protocols for the synthesis of (1→1)‐ and (1→6)‐linked C‐disaccharides have been developed (see scheme). A one‐pot Au‐catalyzed alkynol cycloisomerization followed by BF3⋅Et2O, Et3SiH reduction has been established as the key reaction for C‐disaccharide synthesis including all possible pyran–pyran, furan–furan, and pyran–furan combinations.
- Subjects
CHEMICAL research; DISACCHARIDES; CYCLOISOMERIZATION; DEOXYGENATION; LACTONES; YNOLS; GLYCOSIDES
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 45, p15109
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201302252