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- Title
Crystalline Structural Intermediates of a Breathing Metal-Organic Framework That Functions as a Luminescent Sensor and Gas Reservoir.
- Authors
Xiao, Juan; Wu, Yuan; Li, Mian; Liu, Bao‐Yu; Huang, Xiao‐Chun; Li, Dan
- Abstract
A rod‐packing, breathing MOF (1), with two crystalline structural intermediates (1 a and 1 b; H2btca=benzotriazole‐5‐carboxylic acid) has been investigated. An underlying net approach for analyzing possible breathing MOFs, and a set of geometric parameters that can quantitatively describe such a breathing structural feature, are suggested. The 3D luminescent MOF is a promising candidate for specific sensors with exceptional sorption capacity.
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 6, p1891
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201203515