We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
New Ru(II) pyrazolone complex catalyzed direct amination of alcohols: A preliminary mechanistic investigation.
- Authors
Dharani, Sivadasan; Kalaiarasi, Giriraj; Lynch, Vincent M.; Prabhakaran, Rathinasabapathi
- Abstract
A novel Ru(II) complex containing 4‐(2‐hydroxybenzyl)‐3‐methyl‐5‐oxo‐2,5‐dihydropyrazole‐1‐carbothioic acid methylamide has been applied as a catalyst for directly aminating alcohols. Preliminary investigation on the reaction mechanism has been done with the help of NMR spectroscopy recorded for regenerated catalysts and an NMR reaction. In addition, a plausible mechanism for the formation of the coupled product has been proposed.
- Subjects
AMINATION; PYRAZOLONES; NUCLEAR magnetic resonance spectroscopy; ALCOHOL
- Publication
Applied Organometallic Chemistry, 2023, Vol 37, Issue 5, p1
- ISSN
0268-2605
- Publication type
Article
- DOI
10.1002/aoc.7076