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- Title
Partitioning of Selected Anisole and Veratrole Derivatives between Water and Anionic Surfactant Micelles.
- Authors
Lewandowski, Andrzej; Szymczyk, Katarzyna; Lognay, Georges C.
- Abstract
The UV absorption spectra of six structurally related derivatives of anisole and veratrole, i.e., anisaldehyde, (E)-anethole, estragole, veratraldehyde, methyleugenol and (E)-methylisoeugenol, were recorded at various concentrations of the anionic surfactants, either sodium lauryl sulfate (SLS) or sodium lauryl ether sulfate (SLES) at T = 298 K. In addition, conductivity and density measurements were made for the SLS and SLES solutions to determine the volumetric properties of the studied surfactants. Next, using the W. Al-Soufi, L. Pińeiro and M. Novo model (APN model) including the pseudo-phase model for micellar solubilization, the values of micelle-water partition coefficients for each perfume-surfactant system were determined. In addition, the relations between the molecular structures of the solute and the head group of the surfactant and the value of the micelle-water partition coefficient as well as the octanol-water one were discussed.
- Subjects
SODIUM dodecyl sulfate; SOLUBILIZATION; ANIONIC surfactants; MOLECULAR structure; MICELLES; ANISOLE; ABSORPTION spectra; SURFACE active agents
- Publication
Molecules, 2020, Vol 25, Issue 24, p5818
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules25245818