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- Title
A Novel One-Dimensional Coordination Polymer Involving Weak Hg—Hg Interactions.
- Authors
Ali Morsali; Rhett Kempe
- Abstract
The novel, stable, one-dimensional coordination polymer [Hg3(dmap)6(μ-OAc)2]n{(ClO4)4}n (1; dmap = 4-(dimethylamino)pyridine) has been synthesized and characterized. Single-crystal X-ray analysis showed that the coordination sphere of the two pertinent, zig-zag-oriented HgII-atoms is different. One type of Hg-atom in the N2O4Hg—HgN2O4 environment is seven-coordinate, with a weak Hg—Hg interaction. The other type of HgII-atom in the trans-HgN2O4 units is six-coordinate.
- Publication
Helvetica Chimica Acta, 2005, Vol 88, Issue 8, p2267
- ISSN
0018-019X
- Publication type
Article