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- Title
Highly Regioselective Radical Amination of Allenes: Direct Synthesis of Allenamides and Tetrasubstituted Alkenes.
- Authors
Zhang, Ge; Xiong, Tao; Wang, Zining; Xu, Guoxing; Wang, Xuedan; Zhang, Qian
- Abstract
The first controllable, regioselective radical amination of allenes with N-fluoroarylsulfonimide is described to proceed under very mild reaction conditions. With this methodology, a general and straightforward route for the synthesis of both allenamides and fluorinated tetrasubstituted alkenes was realized from a wide range of terminal and internal allenes.
- Subjects
REGIOSELECTIVITY (Chemistry); AMINATION; ALLENE; ALLENAMIDES; ALKENES
- Publication
Angewandte Chemie International Edition, 2015, Vol 54, Issue 43, p12649
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201506066