We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Gold-Catalyzed Synthesis of Tetrazoles from Alkynes by CC Bond Cleavage.
- Authors
Gaydou, Morgane; Echavarren, Antonio M.
- Abstract
Golden duality: Tetrazoles are formed by the reaction of alkynes with TMSN3 (TMS=trimethylsilyl) in the presence of iPrOH and the gold(I) catalyst [JohnPhosAu(MeCN)]SbF6. In this transformation gold plays a dual role, first activating the alkyne and then generating a Brønsted acid in situ.
- Subjects
TETRAZOLES; ALKYNE synthesis; GOLD catalysts; CARBON-carbon bonds synthesis; CHEMICAL reactions; TRIMETHYLSILYL compounds
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 50, p13468
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201308076