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- Title
Composition change of uranium perchlorates with organic ligands upon mechanochemical activation of exchange processes.
- Authors
Zazhogin, A. P.; Komyak, A. I.; Umreiko, D. S.
- Abstract
Results of studies on the effect of mechanochemical activation of ligand exchange processes in uranyl perchlorate-dimethylsulfoxide are presented. Spectroscopic data show that mechanical activation of the exchange process in this system results in the replacement of H2O in the first coordination sphere of uranyl UO by DMSO to form nanocrystals with a defined ligand sphere. Possible factors governing the noted features are considered.
- Subjects
ACTIVATION (Chemistry); URANIUM spectra; PERCHLORATES; SPECTRUM analysis; NANOCRYSTALS
- Publication
Journal of Applied Spectroscopy, 2008, Vol 75, Issue 2, p219
- ISSN
0021-9037
- Publication type
Article
- DOI
10.1007/s10812-008-9027-4