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- Title
<sup>119</sup>Sn Mössbauer characterization of self assembled organotin(IV) complexes with Schiff bases containing amino acetate skeletons.
- Authors
Basu, Smita; Mizar, Archana; Baul, Tushar S. Basu; Rivarola, Eleonora
- Abstract
Several organotin(IV) compounds, viz., diorganotin(IV) compounds of the types Ph2SnLH (monomer), nBu2SnLH·OH2 (monomer), [Me2SnLH·OH2]2 (centrosymmetric dimer), [nBu2SnLH]3 (cyclic trinuclear), [Ph2SnLH] n (polymer), {[nBu2Sn(LH)]2O}2 (centrosymmetric tetranuclear), dinuclear di-/tri-mixed organotin(IV) compounds Ph2SnLH·Ph3SnCl (monomer) and triorganotin(IV) compounds of the types [Bz3SnLH]2 (centrosymmetric dimer) and [Me3SnL1H] n (Polymer) (LH = Schiff base carboxylate) have been studied in the solid state at liquid nitrogen temperature using 119Sn Mössbauer spectroscopy. The tin coordination geometry of the compounds determined from crystallography was correlated with the 119Sn Mössbauer results.
- Subjects
ORGANOTIN compounds; SPECTRUM analysis; COMPLEX compounds; GEOMETRY; MONOMERS; TEMPERATURE
- Publication
Hyperfine Interactions, 2008, Vol 185, Issue 1-3, p95
- ISSN
0304-3843
- Publication type
Article
- DOI
10.1007/s10751-008-9817-3