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- Title
Super-hydration and reduction of manganese oxide minerals at shallow terrestrial depths.
- Authors
Yun, Seohee; Hwang, Huijeong; Hwang, Gilchan; Kim, Yeongkyoo; Blom, Douglas; Vogt, Thomas; Post, Jeffrey E.; Jeon, Tae-Yeol; Shin, Tae Joo; Zhang, Dong-Zhou; Kagi, Hiroyuki; Lee, Yongjae
- Abstract
Manganese oxides are ubiquitous marine minerals which are redox sensitive. As major components of manganese nodules found on the ocean floor, birnessite and buserite have been known to be two distinct water-containing minerals with manganese octahedral interlayer separations of ~7 Å and ~10 Å, respectively. We show here that buserite is a super-hydrated birnessite formed near 5 km depth conditions. As one of the most hydrous minerals containing ca. 34.5 wt. % water, super-hydrated birnessite, i.e., buserite, remains stable up to ca. 70 km depth conditions, where it transforms into manganite by releasing ca. 24.3 wt. % water. Subsequent transformations to hausmannite and pyrochroite occur near 100 km and 120 km depths, respectively, concomitant with a progressive reduction of Mn4+ to Mn2+. Our work forwards an abiotic geochemical cycle of manganese minerals in subduction and/or other aqueous terrestrial environments, with implications for water storage and cycling, and the redox capacity of the region. The enigmatic relationship of birnessite and buserite, the two most representative phases in submarine nodules, has been established to reveal that buserite is a super-hydrated form of birnessite, forming at shallow terrestrial depth in the presence of water
- Subjects
OXIDE minerals; MANGANESE oxides; OCEAN bottom; WATER storage; GEOCHEMICAL cycles; HYDROLOGIC cycle
- Publication
Nature Communications, 2022, Vol 13, Issue 1, p1
- ISSN
2041-1723
- Publication type
Article
- DOI
10.1038/s41467-022-29328-y