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- Title
Arundo donax L Processing in Catalyzed Butanol–Water Media in the Scope of Lignocellulose Biorefineries.
- Authors
Rivas, Sandra; Baldassari, Rebecca; Parajó, Juan Carlos; Raspolli Galletti, Anna M.
- Abstract
Arundo donax L samples, before or after aqueous extraction to remove extractives, were subjected to chemical fractionation in H2SO4-catalyzed mixtures of 1-butanol and water. The partial miscibility of 1-butanol and water at room temperature allowed the separation of the three major feedstock components in separate streams (lignin, accumulated in the 1-butanol-rich phase; hemicellulose-derived products, accumulated in the aqueous acidic phase; and cellulose, present in the solid phase). The effects of selected variables (temperature, catalyst concentration, reaction time and 1-butanol content of the reaction media) on variables measuring the solid recovery yield and the compositions of phases from fractionation were measured. Using water-extracted A. donax L as a substrate, the best operational conditions enabled 93.2% hemicellulose removal and 85.4% delignification with limited cellulose solubilization (15%). The experimental results provided key information to assess the proposed process in the scope of biorefineries.
- Subjects
GIANT reed; LIGNOCELLULOSE; LIGNIN structure; HEMICELLULOSE; BUTANOL; WATER temperature; CELLULOSE; DELIGNIFICATION
- Publication
Polymers (20734360), 2023, Vol 15, Issue 6, p1553
- ISSN
2073-4360
- Publication type
Article
- DOI
10.3390/polym15061553