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- Title
The Oxygen-Rich Beryllium Oxides BeO<sub>4</sub> and BeO<sub>6</sub>.
- Authors
Zhang, Qingnan; Jerabek, Paul; Chen, Mohua; Zhou, Mingfei; Frenking, Gernot
- Abstract
Two novel isomers of BeO4 with the structures OBeOOO and OBe(O3) in the electronic triplet state have been prepared as well as the known disuperoxide complex Be(O2)2 in solid noble-gas matrices. We also report the synthesis of the oxygen-rich bis(ozonide) complex Be(O3)2 in the triplet state which has a D2 d equilibrium geometry. The molecular structures were identified by infrared absorption spectroscopy with isotopic substitutions as well as quantum chemical calculations.
- Subjects
BERYLLIUM oxide; SUPEROXIDES; MOLECULAR structure; INFRARED absorption; QUANTUM chemistry
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 36, p11021
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201606154