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- Title
Acylsilanes in Iridium-Catalyzed Directed Amidation Reactions and Formation of Heterocycles via Siloxycarbenes.
- Authors
Becker, Peter; Pirwerdjan, Ramona; Bolm, CarstEN
- Abstract
Exposing ortho-amido aroylsilanes to visible light or heat leads to cyclization reactions that provide N-heterocyclic compounds via siloxycarbenes as key intermediates. The previously unreported starting materials have been prepared by directed amidations of aromatic acylsilanes in the presence of an iridium catalyst followed by N-alkylation.
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 51, p15713
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201508501