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- Title
Two-Dimensional Covalent Organic Frameworks for Carbon Dioxide Capture through Channel-Wall Functionalization.
- Authors
Huang, Ning; Chen, Xiong; Krishna, Rajamani; Jiang, Donglin
- Abstract
Ordered open channels found in two-dimensional covalent organic frameworks (2D COFs) could enable them to adsorb carbon dioxide. However, the frameworks' dense layer architecture results in low porosity that has thus far restricted their potential for carbon dioxide adsorption. Here we report a strategy for converting a conventional 2D COF into an outstanding platform for carbon dioxide capture through channel-wall functionalization. The dense layer structure enables the dense integration of functional groups on the channel walls, creating a new version of COFs with high capacity, reusability, selectivity, and separation productivity for flue gas. These results suggest that channel-wall functional engineering could be a facile and powerful strategy to develop 2D COFs for high-performance gas storage and separation.
- Subjects
CARBON dioxide; GAS absorption &; adsorption; SEPARATION of gases; GAS storage; CARBOXYLIC acids
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 10, p3029
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201411262