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- Title
Chemoselective noncatalytic addition of secondary phosphine chalcogenides to citral.
- Authors
Gusarova, N.; Ivanova, N.; Konovalova, N.; Albanov, A.; Sinegovskaya, L.; Avseenko, N.; Sukhov, B.; Mikhaleva, A.; Gusarov, A.; Trofimov, B.
- Abstract
Addition of secondary phosphine oxides, phosphine sulfides and phosphine selenides to 3,7-dimethyl-2,6-octadienal (citral) (48–50°C, THF, argon) proceeds exclusively to the aldehyde group giving rise to new polyfunctional tertiary phosphine chalcogenides with diene and hydroxyl moieties in high preparative yield (up to 80%).
- Subjects
SULFIDES; SELENIDES; ARGON; ALDEHYDES; CHALCOGENIDES; INORGANIC compounds
- Publication
Russian Journal of General Chemistry, 2007, Vol 77, Issue 3, p409
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363207030139