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- Title
Merrilliadione - a Rare Isopropyl (13→11)- abeo-9,11- seco Abietane Diterpene from Illicium merrillianum.
- Authors
Tian, Xinhui; Yue, Rongcai; Zhang, Shoude; Shen, Yunheng; Ye, Ji; Shan, Lei; Li, Huiliang; Wen, Bo; Xu, Xike; Zhang, Weidong
- Abstract
Merrilliadione ( 1), a new diterpene with a unique isopropyl (13→11)- abeo-9,11- seco-abietane skeleton, and two new abietane diterpenoids ( 2 and 3) were isolated from Illicium merrillianum. This is the first report of an isopropyl (13→11)- abeo-9,11- seco abietane diterpenoid. The structures of 1- 3 were established by comprehensive spectroscopic analysis, single-crystal X-ray diffraction, and quantum chemical computation of electronic circular dichroism (ECD) spectra.
- Subjects
ABIETANE; ILLICIUM; SPECTRUM analysis; CIRCULAR dichroism; X-ray diffraction
- Publication
European Journal of Organic Chemistry, 2014, Vol 2014, Issue 22, p4753
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201402406