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- Title
Recent Highlights in Ketenimine Chemistry.
- Authors
Alajarin, Mateo; Marin-Luna, Marta; Vidal, Angel
- Abstract
Selected recent developments in the chemistry of ketenimines are presented, demonstrating that heterocumulenes of this class are versatile reactive intermediates in the synthesis of nitrogenated heterocycles. This microreview includes examples of intramolecular nucleophilic and radical additions, biradical cyclizations, 4π- and 6π-electrocyclic ring closures, [2+2], [3+2] and [4+2] cycloadditions, ketenimine-to-nitrile rearrangements and 1,3-X, 1,5-X and 1,5-H shifts.
- Publication
European Journal of Organic Chemistry, 2012, Vol 2012, Issue 29, p5637
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201200383