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- Title
One-Pot Synthesis of O-Allylhydroxylamines through the Organocatalytic Oxidation of Tertiary Allylic Amines Followed by a [2,3]-Meisenheimer Rearrangement.
- Authors
Theodorou, Alexis; Limnios, Dimitris; Kokotos, Christoforos G.
- Abstract
A cheap, green, and highly efficient one-pot method for the synthesis of O-protected allylic alcohols is described. By utilizing 2,2,2-trifluoroacetophenone as the organocatalyst and H2O2 as the oxidant, a variety of allylic amine N-oxides were synthesized, which upon heating are converted to the final products through a [2,3]-Meisenheimer rearrangement.
- Subjects
ALLYL alcohol synthesis; TRIFLUOROACETIC acid; ORGANOCATALYSIS; ALLYLIC amination; OXIDATION; MEISENHEIMER complexes
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 13, p5238
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201406173