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- Title
Platinum Complexes Containing Pyramidalized Germanium and Tin Dihalide Ligands Bound through σ,σ M=E Multiple Bonds.
- Authors
Hupp, Florian; Ma, Mengtao; Kroll, Franziska; Jimenez ‐ Halla, J. Oscar C.; Dewhurst, Rian D.; Radacki, Krzysztof; Stasch, Andreas; Jones, Cameron; Braunschweig, Holger
- Abstract
We present the isolation of the first mononuclear dihalogermylene, and mono- and dinuclear stannylene complexes of transition metals. These exhibit exceptionally pyramidalized Group 14 centers. Additionally, removal of the halide substituents from the Ge/Sn atom was successfully performed in two ways, halide abstraction and reduction, leading to a variety of unusual structural motifs.
- Subjects
TRANSITION metal complexes; PLATINUM compounds; SEPARATION (Technology); HALIDES; ABSTRACTION process (Catalysis); CHEMICAL reduction
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 51, p16888
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201404342