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- Title
INVESTIGATING CATALYTIC OXIDATION OF CYCLOHEXENE USING Fe(II) AND Co(II)PHTHALOCYANINE COMPLEXES.
- Authors
Sharanakumar, T. M.; Praveen Kumar, N. Y.; Mounesh; Vindhya, R.; Venugopal Reddy, K. R.
- Abstract
The Carbutamide substituted Fe(II) phthalocyanine (CBTAFePc) and Co(II) phthalocyanine (CBTACoPc) complex was synthesized from tetra carboxylic acid Fe(II) phthalocyanine (FeTcPc) and tetra carboxylic acid Co(II) phthalocyanine (CoTcPc) with Carbutamide (CBTA) by linkage of amide has been developed. The macrocyclic molecules have high molecular weight and the molecule is completely soluble in Dimethylformamide and Dimethylsulfoxide. The synthesized complexes were confirmed by FTIR, Ultraviolet-Visible, PXRD, Mass, C,H,N and Thermo-gravimetric techniques. The catalytic activity of CBTAFePc and CBTAFePc were analyzed in the oxidation of Cyclohexene with various parameters like temperature, types of oxidants, oxidant/cat ratio, and subs/catalyst ratio affect the oxidation reactions were investigate the optimum conditions of catalysts. CBTAFePc shows excellent catalytic results on oxidation of Cyclohexene with the highest yield with good selectivity. The overall results show that the CBTAFePc complex exhibits an excellent catalyst compared with the CBTACoPc complex for investigation of the oxidation of Cyclohexene.
- Subjects
CATALYTIC oxidation; CATALYSTS; CYCLOHEXENE; CATALYTIC activity; MOLECULAR weights; CARBOXYLIC acids
- Publication
Rasayan Journal of Chemistry, 2021, Vol 14, Issue 3, p1761
- ISSN
0974-1496
- Publication type
Article
- DOI
10.31788/RJC.2021.1436386