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- Title
Indium Tribromide‐Catalysed Transfer‐Hydrogenation: Expanding the Scope of the Hydrogenation and of the Regiodivergent DH or HD Addition to Alkenes.
- Authors
Li, Luomo; Hilt, Gerhard
- Abstract
The transfer‐hydrogenation as well as the regioselective and regiodivergent addition of H−D from regiospecific deuterated dihydroaromatic compounds to a variety of 1,1‐di‐ and trisubstituted alkenes was realised with InBr3 in dichloro(m)ethane. In comparison with the previously reported BF3⋅Et2O‐catalysed process, electron‐deficient aryl‐substituents can be applied reliably and thereby several restrictions could be lifted, and new types of substrates could be transformed successfully in hydrodeuterogenation as well as deuterohydrogenation transfer‐hydrogenation reactions.
- Subjects
INDIUM; ALKENES; ETHANES; CATALYSIS; HYDROGENATION
- Publication
Chemistry - A European Journal, 2021, Vol 27, Issue 43, p11221
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202101259