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- Title
NMR study of localization and mobility of 1-phenylethanol enantiomers in homochiral metal-organic sorbent Zn<sub>2</sub>(bdc)(S-lac)(dmf).
- Authors
Gallyamov, M. R.; Yutkin, M. P.; Moroz, N. K.; Kozlova, S. G.; Gabuda, S. P.
- Abstract
Structural features of localization of chiral isomers of 1-phenylethanol (R-PhEtOH and S-PhEtOH) and their mobility activation in homochiral metal-organic [Zn2(bdc)(S-lac)(dmf)] sorbent were studied with ¹H and 13C NMR methods. 13C NMR chemical shifts do not show obvious advantage of selective interaction of molecule guests. But activation molecular mobility of S-PhEtOH and RPhEtOH clearly indicates that stabilization of [Zn2(bdc)(S-lac)(dmf)]·S-PhEtOH structure is more preferable than stabilization of [Zn2(bdc)(S-lac)(dmf)]·R-PhEtOH structure.
- Subjects
NUCLEAR magnetic resonance; ENANTIOMERS; SORBENTS; ENANTIOSELECTIVE catalysis; CHIRAL recognition
- Publication
Magnetic Resonance in Chemistry, 2015, Vol 53, Issue 8, p578
- ISSN
0749-1581
- Publication type
Article
- DOI
10.1002/mrc.4262