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- Title
Study of the structure of a new heterometallic complex based on copper(II) ketoiminate [ cis-Cu(ki)·Pb(hfa)].
- Authors
Baidina, I.; Krisyuk, V.; Korol'kov, I.; Stabnikov, P.
- Abstract
The cocrystallization method is used to obtain a new volatile heterometallic complex of the composition [Cu(ki)·Pb(hfa)], where ki = 2-iminopentan-4-onate and hfa = hexafluoroacetylacetonate. The crystallographic data for CHCuFNOPb: a = 10.6729(5)Å, b = 10.7712(5)Å., c = 13.4779(5)Å.; α = 79.1020(10)°, β = 84.5140(10)°, γ = 66.2470(10)°, P-1 space group, Z = 2, d = 2.102 g/cm. The compound has a molecular structure built of individual Cu...Pb...Pb...Cu-type tetramers. The Cu...Pb and Pb...Pb distances in the tetramer are 3.454. and 4.122. respectively; the Cu-Pb-Pb angle is 160.7°.
- Subjects
METAL complexes; ORGANOCOPPER compounds; CRYSTALLIZATION; MOLECULAR structure; VOLATILE organic compounds; KETONES
- Publication
Journal of Structural Chemistry, 2011, Vol 52, Issue 5, p1008
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S0022476611050283