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- Title
A durable and pH-universal self-standing MoC–Mo<sub>2</sub>C heterojunction electrode for efficient hydrogen evolution reaction.
- Authors
Liu, Wei; Wang, Xiting; Wang, Fan; Du, Kaifa; Zhang, Zhaofu; Guo, Yuzheng; Yin, Huayi; Wang, Dihua
- Abstract
Efficient water electrolyzers are constrained by the lack of low-cost and earth-abundant hydrogen evolution reaction (HER) catalysts that can operate at industry-level conditions and be prepared with a facile process. Here we report a self-standing MoC–Mo2C catalytic electrode prepared via a one-step electro-carbiding approach using CO2 as the feedstock. The outstanding HER performances of the MoC–Mo2C electrode with low overpotentials at 500 mA cm−2 in both acidic (256 mV) and alkaline electrolytes (292 mV), long-lasting lifetime of over 2400 h (100 d), and high-temperature performance (70 oC) are due to the self-standing hydrophilic porous surface, intrinsic mechanical strength and self-grown MoC (001)–Mo2C (101) heterojunctions that have a ΔGH* value of −0.13 eV in acidic condition, and the energy barrier of 1.15 eV for water dissociation in alkaline solution. The preparation of a large electrode (3 cm × 11.5 cm) demonstrates the possibility of scaling up this process to prepare various carbide electrodes with rationally designed structures, tunable compositions, and favorable properties. Scalable fabrication of Low-cost hydrogen evolution reaction (HER) catalysts that can operate at industry-relevant conditions is highly needed for efficient water electrolyzers. Here the authors show a scalable synthesis of a MoC-Mo2C heterojunction electrode with efficient HER activity and high stability at industrial conditions.
- Subjects
HYDROGEN evolution reactions; STANDARD hydrogen electrode; HETEROJUNCTIONS; ELECTRODE performance; ALKALINE solutions; ACTIVATION energy
- Publication
Nature Communications, 2021, Vol 12, Issue 1, p1
- ISSN
2041-1723
- Publication type
Article
- DOI
10.1038/s41467-021-27118-6