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- Title
Chemical Non-Innocence of an Aliphatic PNP Pincer Ligand.
- Authors
Schneck, Felix; Finger, Markus; Tromp, Moniek; Schneider, Sven
- Abstract
The synthesis of the divinylamido PNP nickel(II) complex [NiBr{N(CHCHP tBu2)2}] is reported. This compound exhibits reversible, ligand-centered oxidation and protonation reactions. The resulting pincer chemical non-innocence can be utilized for benzylic C−H hydrogen atom abstraction. The thermochemistry and kinetics of hydrogen atom transfer were examined.
- Subjects
ALIPHATIC compounds; NICKEL compounds; OXIDATION; LIGANDS (Chemistry); PROTON transfer reactions; CARBON-hydrogen bonds
- Publication
Chemistry - A European Journal, 2017, Vol 23, Issue 1, p33
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201604407