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- Title
'(Diphosphine)Nickel'-Catalyzed Negishi Cross-Coupling: An Experimental and Theoretical Study.
- Authors
Nicolas, Emmanuel; Ohleier, Alexia; D'Accriscio, Florian; Pécharman, Anne ‐ Frédérique; Demange, Matthieu; Ribagnac, Philippe; Ballester, Jorge; Gosmini, Corinne; Mézailles, Nicolas
- Abstract
The use of a strongly donating '(bis-dialkylphosphine)Ni' fragment promotes the catalytic coupling of a large range of ArCl and ArZnCl derivatives under mild conditions. Stoichiometric mechanistic investigations and DFT calculations prove that a Ni0/NiII cycle is operative in this system.
- Subjects
COUPLING reactions (Chemistry); DIPHOSPHINE; NICKEL catalysts; ARGON chlorides; DENSITY functional theory
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 21, p7690
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201500192