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- Title
Production of Hydrogen-Rich Gas by Formic Acid Decomposition over CuO-CeO2/γ-Al2O3 Catalyst.
- Authors
Pechenkin, Alexey; Badmaev, Sukhe; Belyaev, Vladimir; Sobyanin, Vladimir
- Abstract
Formic acid decomposition to H2-rich gas was investigated over a CuO-CeO2/γ-Al2O3 catalyst. The catalyst was characterized by XRD, HR TEM and EDX methods. A 100% conversion of formic acid was observed over the copper-ceria catalyst under ambient pressure, at 200–300 °C, N2:HCOOH = 75:25 vol.% and flow rate 3500–35,000 h−1 with H2 yield of 98%, wherein outlet CO concentration is below the equilibrium data (<0.5 vol.%). The copper-ceria catalyst proved to be promising for multifuel processor application, and the H2 generation from dimethoxymethane, methanol, dimethyl ether and formic acid on the same catalyst for fuel cell supply.
- Subjects
FORMIC acid; ACID catalysts; CATALYSTS; METHYL ether; FUEL cells; COPPER catalysts
- Publication
Energies (19961073), 2019, Vol 12, Issue 18, p3577
- ISSN
1996-1073
- Publication type
Article
- DOI
10.3390/en12183577