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- Title
Acrolein Oxidation to Acrylic Acid on Mo/V/W-Mixed Oxide Catalysts.
- Authors
Drochner, Alfons; Kampe, Philip; Menning, Nadine; Blickhan, Nina; Jekewitz, Tim; Vogel, Herbert
- Abstract
Oxidation of acrolein to acrylic acid on Mo/V/W-mixed oxide catalysts has been studied by means of the isotopic exchange method steady-state isotopic transient kinetic analysis (SSITKA). As a result of these isotopic exchanges performed with 16O2 and 18O2, some new mechanistic details could be obtained. Acrolein exchanges its oxygen with oxygen of the mixed oxide catalyst. Additionally, the kinetics of the different isotopologues is significantly influenced by oxygen exchange reactions between the surface and the bulk sites. From the SSITKA results, an extended reaction model has been deduced. Thus, the experimentally gained data of the individual isotopologue kinetics could be verified by modeling.
- Subjects
ACROLEIN; OXIDATION; OXIDES; ISOTOPOLOGUES; OXYGEN; CATALYSIS
- Publication
Chemical Engineering & Technology, 2014, Vol 37, Issue 3, p398
- ISSN
0930-7516
- Publication type
Article
- DOI
10.1002/ceat.201300797