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- Title
Lowering Molecular Symmetry To Improve the Morphological Properties of the Hole‐Transport Layer for Stable Perovskite Solar Cells.
- Authors
Wang, Xuchao; Zhang, Jing; Yu, Shuwen; Yu, Wei; Fu, Ping; Liu, Xuan; Tu, Dandan; Guo, Xin; Li, Can
- Abstract
Abstract: Inspired by the structural feature of the classical hole‐transport material (HTM), Spiro‐OMeTAD, many analogues based on a highly symmetrical spiro‐core were reported for perovskite solar cells (PSCs). However, these HTMs were prone to crystallize because of the high molecular symmetry, forming non‐uniform films, unfavorable for the device stability and large‐area processing. By lowering the symmetry of spiro‐core, we report herein a novel spirobisindane‐based HTM, Spiro‐I, which could form amorphous films with high uniformity and morphological stability. Compared to the Spiro‐OMeTAD‐based PSCs, those containing Spiro‐I exhibit similar efficiencies for small area but higher ones for large area (1 cm2), and especially much higher air stability (retaining 80 % of initial PCE after 2400 h storage without encapsulation). Moreover, the Spiro‐I can be synthesized from a cheap starting material bisphenol A and used with a small amount for the device fabrication.
- Subjects
SOLAR cells; PEROVSKITE; BISPHENOL A; MICROENCAPSULATION; SPIRO compounds
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 38, p12709
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201807402