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- Title
Water-in-Supercritical CO<sub>2</sub> Microemulsion Stabilized by a Metal Complex.
- Authors
Luo, Tian; Zhang, Jianling; Tan, Xiuniang; Liu, Chengcheng; Wu, Tianbin; Li, Wei; Sang, Xinxin; Han, Buxing; Li, Zhihong; Mo, Guang; Xing, Xueqing; Wu, Zhonghua
- Abstract
Herein we propose for the first time the utilization of a metal complex for forming water-in-supercritical CO2 (scCO2) microemulsions. The water solubility in the metal-complex-stabilized microemulsion is significantly improved compared with the conventional water-in-scCO2 microemulsions stabilized by hydrocarbons. Such a microemulsion provides a promising route for the in situ CO2 reduction catalyzed by a metal complex at the water/scCO2 interface.
- Subjects
MICROEMULSIONS; WATER; SUPERCRITICAL carbon dioxide; METAL complexes; PHOTOCATALYSIS
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 43, p13731
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201608695