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- Title
A syn-Selective Aza-Aldol Reaction of Boron Aza-Enolates Generated from N-Sulfonyl-1,2,3-Triazoles and 9-BBN-H.
- Authors
Miura, Tomoya; Nakamuro, Takayuki; Miyakawa, Sho; Murakami, Masahiro
- Abstract
A syn-selective aza-aldol reaction of boron aza-enolates, generated from N-sulfonyl-1,2,3-triazoles and 9-BBN-H, is reported. It provides a sequential one-pot procedure for the stereoselective construction of 1,3-amino alcohols, having contiguous stereocenters, starting from terminal alkynes.
- Subjects
ENOLATES; TRIAZOLES synthesis; AZA compounds; BORON compounds; STEREOSELECTIVE reactions
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 30, p8874
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201603270