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- Title
Reaction of 5-Hydrazono-1,2,3-thiadiazoles with Toluene and Xylene in the Presence of PCl<sub>5</sub>.
- Authors
Glukhareva, T. V.; Dyudya, L. V.; Morzherin, Yu. Yu.; Tkachev, A. V.; Bakulev, V. A.
- Abstract
The treatment of 5-hydrazono-1,2,3-thiadiazoles by phosphorus pentachloride in toluene or xylene leads to an anomalous Dimroth rearrangement and the reaction of the mercapto function formed with the methyl group of the solvent to give 5-benzylmercapto-1,2,3-triazole.
- Subjects
THIADIAZOLES; THIAZOLES; TRIAZOLES; REARRANGEMENTS (Chemistry); CHEMICAL reactions; PHOSPHORUS compounds; TOLUENE; XYLENE
- Publication
Chemistry of Heterocyclic Compounds, 2003, Vol 39, Issue 1, p126
- ISSN
0009-3122
- Publication type
Article
- DOI
10.1023/A:1023041329732