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- Title
Converting Brownmillerite to Alternate Layers of Oxygen‐Deficient and Conductive Nano‐Sheets with Enhanced Thermoelectric Properties.
- Authors
Hu, Songbai; Han, Wenqiao; Li, Xiaowen; Ye, Mao; Lu, Yao; Jin, Cai; Liu, Qi; Wang, Junling; He, Jiaqing; Cazorla, Claudio; Zhu, Yuanmin; Chen, Lang
- Abstract
Introducing large oxygen deficiencies while retaining low resistivity is important for enhancing the overall thermoelectric properties in 3d transition‐metal oxides. In this study, a new synthesis route to reconstruct the insulating brownmillerite SrCoO2.5 is adapted. Through a step‐by‐step nano‐blocks modification, a series of highly‐conductive layered structures is evolved, which are [Sr2O2H2]0.5CoO2, [Sr2O2]0.4CoO2, and [Sr2CoO3]0.57CoO2, while still retaining considerable Seebeck coefficient (≈100 µV K−1). Coexistence of low resistivity and high oxygen deficiency is realized in the latter two polymorphs by forming a majority of sintered oxygen vacancies in the rock‐salt layer and a minority of normal oxygen vacancies in the CoO2 layer. A room‐temperature in‐plane power factor of 3.6 mW K−2 m−1, power output density of 4.5 W m−2 at a temperature difference of 28 K, and an out‐of‐plane thermal conductivity of 0.33 W K−1 m−1 are obtained in the [Sr2O2]0.4CoO2 thin film that exhibits the highest oxygen deficiency (δ = 2.95), which is on par with Bi2Te3, the benchmark. It is pointed out that proper distribution of oxygen vacancy is essential in tailoring the physical and chemical properties of transition‐metal oxides. The sintered/normal oxygen vacancy layer model provides guidance to the exploration of materials with both low electric resistivity and thermal conductivity.
- Subjects
THERMOELECTRIC materials; BISMUTH telluride; SEEBECK coefficient; ELECTRICAL resistivity; TRANSITION metal oxides; THERMAL conductivity; POWER density
- Publication
Advanced Energy Materials, 2022, Vol 12, Issue 28, p1
- ISSN
1614-6832
- Publication type
Article
- DOI
10.1002/aenm.202201469