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- Title
Norbornenes in Inverse Electron-Demand Diels-Alder Reactions.
- Authors
Vrabel, Milan; Kölle, Patrick; Brunner, Korbinian M.; Gattner, Michael J.; López‐Carrillo, Verónica; de Vivie‐Riedle, Regina; Carell, Thomas
- Abstract
Significant differences in the reactivity of norbornene derivatives in the inverse electron‐demand Diels–Alder reaction with tetrazines were revealed by kinetic studies. Substantial rate enhancement for the exo norbornene isomers was observed (see scheme). Quantum‐chemical calculations were used to rationalize and support the observed experimental data.
- Subjects
DIELS-Alder reaction; CHEMICAL reactions; PARTICLES (Nuclear physics); ALKENES; TETRAZINE
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 40, p13309
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201301838