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- Title
Gold- N-Heterocyclic Carbene Complexes of Mineral Acids.
- Authors
Brill, Marcel; Nahra, Fady; Gómez‐Herrera, Alberto; Zinser, Caroline; Cordes, David B.; Slawin, Alexandra M. Z.; Nolan, Steven P.
- Abstract
We have synthesized and characterized new gold-N-heterocyclic carbene (NHC) complexes derived from the deprotonation of mineral acids. The use of sulfuric acid was a particularly interesting case. These complexes were tested in known gold-catalyzed reactions, such as the hydration of alkynes and the Meyer-Schuster rearrangement. They proved to be highly efficient in both reactions.
- Subjects
HETEROCYCLIC chemistry; PROTON transfer reactions; SULFURIC acid; ALKYNES; ORGANOMETALLIC chemistry
- Publication
ChemCatChem, 2017, Vol 9, Issue 1, p117
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.201601290